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The Element That Could Change the World

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Schematic depicts the inner workings of a vanadium battery, now in use in a Utah plant, that can supply 250 kilowatts for eight hours.

Making green energy work may depend on three unlikely heroes: an Australian engineer, a battery, and the element vanadium.

by Bob Johnstone

February 27, 2008, was a bad day for renewable energy. A cold front moved through West Texas, and the winds died in the evening just as electricity demand was peaking. Generation from wind power in the region rapidly plummeted from 1.7 gigawatts to only 300 megawatts (1 megawatt is enough to power about 250 average-size houses). The sudden loss of electricity supply forced grid operators to cut power to some offices and factories for several hours to prevent statewide blackouts.

By the next day everything was back to normal, but the Texas event highlights a huge, rarely discussed challenge to the adoption of wind and solar power on a large scale. Unlike fossil fuel plants, wind turbines and photovoltaic cells cannot be switched on and off at will: The wind blows when it blows and the sun shines when it shines, regardless of demand. Even though Texas relies on wind for just over 3 percent of its electricity, that is enough to inject uncertainty into the state's power supplies. The problem is sure to grow more acute as states and utilities press for the expanded use of zero-carbon energy. Wind is the fastest-growing power source in the United States, solar is small but also building rapidly, and California is gearing up to source 20 percent of its power from renewables by 2017.

Experts reckon that when wind power provides a significant portion of the electricity supply (with "significant" defined as about 10 percent of grid capacity), some form of energy storage will be essential to keeping the grid stable. "Without storage, renewables will find it hard to make it big," says Imre Gyuk, manager of energy systems research at the U.S. Department of Energy.

Fortunately, there is a promising solution on the horizon: an obscure piece of technology known as the vanadium redox flow battery. This unusual battery was invented more than 20 years ago by Maria Skyllas-Kazacos, a tenacious professor of electro­chemistry at the University of New South Wales in Sydney, Australia. The vanadium battery has a marvelous advantage over lithium-ion and most other types of batteries. It can absorb and release huge amounts of electricity at the drop of a hat and do so over and over, making it ideal for smoothing out the flow from wind turbines and solar cells.

Skyllas-Kazacos's invention, in short, could be the thing that saves renewable energy's bacon.

To the engineers who maintain the electrical grid, one of the greatest virtues of a power supply is predictability, and that is exactly why renewable energy gives them the willies. Nuclear- and fossil fuel–powered plants produce electricity that is, in industry speak, "dispatchable"; that means it can be controlled from second to second to keep the grid balanced, so the amount of energy being put into the wires exactly matches demand. If the grid goes out of balance, power surges can damage transmission lines and equipment. Generators are therefore designed to protect themselves by going off-line if the grid becomes unstable. Sometimes this can amplify a small fluctuation into a cascading disaster, which is what happened in the northeastern United States and eastern Canada in August 2003, plunging 50 million people into a blackout. Unless the reliability of renewable energy sources can be improved, as these sources contribute more and more electricity to the grid, engineers will have an increasingly difficult time keeping the system balanced. This raises the specter of more blackouts, which nobody would tolerate. "We want to make renewables truly dispatchable so we can deliver given amounts of electricity at a given time," Gyuk says.

The way to make renewables more reliable is to store the excess electricity generated during times of plenty (when there are high winds, for instance, or strong sun) and release it later to match the actual demand. Utilities have been using various storage techniques for decades. Hydroelectric plants, for instance, often draw on reservoirs to generate additional electricity at peak times, and then pump some of the water back uphill in off-peak periods. Compressed air is another, less common form of large-scale energy storage. It can be pumped into underground cavities and tapped later. These technologies have been suggested as ways of storing renewable energy, but both approaches rely on unusual geographical conditions.

"For most of us right now, the real key to effective storage is batteries," says

, senior vice president of transmission and distribution at Southern California Edison. Specifically, what is needed is a battery that can store enough energy to pull an entire power station through a rough patch, can be charged and discharged over and over, and can release large amounts of electricity at a moment's notice. Several promising battery technologies are already in early-stage commercialization, but the vanadium battery may have the edge in terms of scalability and economy.

http://discovermagazine.com/2008/oct/29-th...hange-the-world

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sweet. I'm for having many answers for the energy question.

"The fact that we are here today to debate raising America’s debt limit is a sign of leadership failure. It is a sign that the U.S. Government can’t pay its own bills. It is a sign that we now depend on ongoing financial assistance from foreign countries to finance our Government’s reckless fiscal policies."

Senator Barack Obama
Senate Floor Speech on Public Debt
March 16, 2006



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